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摘 要:提出在部分组分已知的气相色谱灰色体系中,利用已知组分的保留指数和保留时间推算死时间和正构烷烃的保留时间,再计算未知组分保留时间的方法。结果显示,在已知组分不是太少的情况下,该方法计算的死时间和正构烷烃的保留时间与实验值吻合,预测的保留指数也有较高的精度。
Abstract:In
order to obtain the retention indices of unknown components in gas
chromatography, a method using retention indices and retention times of
known components to calculate the dead time and retention times of the
corresponding normal alkanes was developed. The results showed that the
estimation of the dead time and the retention times of the normal
alkanes and the further prediction of the retention indices of unknown
components were quite satisfactory when the number of the known
components included in calculation was not too small. |
作者单位:杜一平(湖南大学化学计量学和化学传感技术研究所,化学化工学院,长沙
410082) 崔卉(湖南大学化学计量学和化学传感技术研究所,化学化工学院,长沙 410082) 梁逸曾(湖南大学化学计量学和化学传感技术研究所,化学化工学院,长沙 410082) 参考文献: [1]Shen Hailin, Liang
Yizeng, Yu Ruqin, Li Xianchen, Sun Xinxi. Science in China (Series B),
1998, 41:21 原载于《分析化学》2001 Vol.29 No.1 P.15-18 http://www.periodicals.com.cn/qikan/periodical/fxhx/fxhx2001/0101/0101ml.htm |